Two-Dimensional Superlattices: synthesis, stability, and bandgap control
Keywords:
2D materials, monolayer superlattices, domain boundariesAbstract
This article constitutes a brief review of recent results related to the experimental realization of one-dimensional interfaces between two-dimensional (2D) materials, along with their mechanical and electronic properties. In the current lore of 2D materials, the formation of spatially periodic domains of different materials constitutes a versatile way to enhance the range of electronic properties and phenomena that can be accessed for fundamental studies and technological applications. Mechanically, the domain boundaries are stable, but can become wrinkled or wavy under certain conditions. In terms of electronic properties, superlattices made of hybrid graphene and boron nitride domains can exhibit rich and spin-depedent behaviour: for example, they can be metallic in one spin component and semiconducting in the other, or semiconducting in both spin components with same or with different band gaps. The control parameters for accessing different electronic properties are the type of materials in the superlattices and their domain widths. These findings can be used in future generation electronic and spintronic devices based on 2D superlattices.
References
LI, X., CAI, W., AN, J., KIM, S., NAH, J., YANG, D., PINER, R., VELAMAKANNI, A., JUNG, I., TUTUC, E., BANERJEE, S.K., COLOMBO, L., RUOFF, R.S., Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils, Science, 324, pp. 1312–1314, 2009.
BAE, S., KIM, H., LEE, Y., XU, X., PARK, J.-S., ZHENG, Y., BALAKRISHNAN, J., LEI, T., KIM, H.R., SONG, Y.I., KIM, Y.-J., KIM, K.S., OZYILMAZ, B., AHN, J.-H., HONG, B.H., IIJIMA, S., Roll-to-roll production of 30-inch graphene films for transparent electrodes, Nature Nanotechnology, 5, pp. 574–578, 2010.
SUN, Z., YAN, Z., YAO, J., BEITLER, E., ZHU, Y., TOUR, J.M., Growth of graphene from solid carbon sources, Nature, 468, pp. 549–552, 2010.
REINA, A., JIA, X., HO, J., NEZICH, D., SON, H., BULOVIC, V., DRESSELHAUS, M.S., KONG, J., Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition, Nano Letters, 9, pp. 30–35, 2009.
LEE, K.H., SHIN, H.-J., LEE, J., LEE, I.-Y., KIM, G.-H., CHOI, J.-Y., KIM, S.-W., Large-Scale Synthesis of High-Quality Hexagonal Boron Nitride Nanosheets for Large-Area Graphene Electronics, Nano Letters, 12, pp. 714–718, 2012.
SONG, L., CI, L., LU, H., SOROKIN, P.B., JIN, C., NI, J., KVASHNIN, A.G., KVASHNIN, D.G., LOU, J., YAKOBSON, B.I., AJAYAN, P.M., Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers, Nano Letters, 10, pp. 3209–3215, 2010.
YANG, W., CHEN, G., SHI, Z., LIU, C.-C., ZHANG, L., XIE, G., CHENG, M., WANG, D., YANG, R., SHI, D., WATANABE, K., TANIGUCHI, T., YAO, Y., ZHANG, Y., ZHANG, G., Epitaxial growth of single-domain graphene on hexagonal boron nitride, Nature Materials, 12, pp. 792–797, 2013.
XUE, J., SANCHEZ-YAMAGISHI, J., BULMASH, D., JACQUOD, P., DESHPANDE, A., WATANABE, K., TANIGUCHI, T., JARILLO-HERRERO, P., LEROY, B.J., Scanning tunnelling microscopy and spectroscopy of ultra-flat graphene on hexagonal boron nitride, Nature Materials, 10, pp. 282–285, 2011.
WANG, M., JANG, S.K., JANG, W.-J., KIM, M., PARK, S.-Y., KIM, S.-W., KAHNG, S.-J., CHOI, J.-Y., RUOFF, R.S., SONG, Y.J., LEE, S., A Platform for Large-Scale Graphene Electronics - CVD Growth of Single-Layer Graphene on CVD-Grown Hexagonal Boron Nitride, Advanced Materials, 25, pp. 2746–2752, 2013.
LIU, Z., SONG, L., ZHAO, S., HUANG, J., MA, L., ZHANG, J., LOU, J., AJAYAN, P.M., Direct Growth of Graphene/Hexagonal Boron Nitride Stacked Layers, Nano Letters, 11, pp. 2032–2037, 2011.
RAMASUBRAMANIAM, A., NAVEH, D., TOWE, E., Tunable Band Gaps in Bilayer Graphene-BN Heterostructures, Nano Letters, 11, pp. 1070–1075, 2011.
SUTTER, P., CORTES, R., LAHIRI, J., SUTTER, E., Interface Formation in Monolayer Graphene-Boron Nitride Heterostructures, Nano Letters, 12, pp. 4869–4874, 2012.
CI, L., SONG, L., JIN, C., JARIWALA, D., WU, D., LI, Y., SRIVASTAVA, A., WANG, Z.F., STORR, K., BALICAS, L., LIU, F., AJAYAN, P.M., Atomic layers of hybridized boron nitride and graphene domains, Nature Materials, 9, pp. 430–435, 2010.
Published
Issue
Section
Copyright (c) 2020 The Romanian Journal of Technical Sciences. Applied Mechanics.

This work is licensed under a Creative Commons Attribution 4.0 International License.